Creating a league table

I am trying to create a round robin table to display league info.
My first hurdle I am having trouble with is generating a list with a 1:1 ratio to players in the league.
Like in the picture below, I’d like to assign them letters A-Z but I cant seem to find a way to generate a list like so.

Any tips or functions I should try?

P.S. the picture is from my concept design but implementing it is difficult.

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